The prediction of the mechanical and electric properties of piezoelectric fibre composites has become an active research area in recent years. By means of introducing a boundary layer problem, some new kinds of two-scale finite element methods for solutions to the electric potential and the displacement for composite material in periodic structure under the coupled piezoelectricity are derived. The coupled two-scale relation of the electric potential and the displacement is set up, and some finite element approximate estimates and numerical examples which show the effectiveness of the method are presented.