Concerns double homoclinic loops with orbit flips and two resonant eigenvalues in a four-dimensional system. We use the solution of a normal form system to construct a singular map in some neighborhood of the equilibrium, and the solution of a linear variational system to construct a regular map in some neighborhood of the double homoclinic loops, then compose them to get the important Poincare map. A simple calculation gives explicitly an expression of the associated successor function. By a delicate analysis of the bifurcation equation, we obtain the condition that the original double homoclinic loops are kept, and prove the existence and the existence regions of the large 1-homoclinic orbit bifurcation surface, 2-fold large 1-periodic orbit bifurcation surface, large 2-homoclinic orbit bifurcation surface and their approximate expressions. We also locate the large periodic orbits and large homoclinic orbits and their number.