The rotational dispersion coefficient of the fiber in the turbulent shear flow of fiber suspension was studied theoretically. The function of correlation moment between the different fluctuating velocity gradients of the flow was built firstly. Then the expression, dependent on the characteristic length, time, velocity and a dimensionless parameter related to the effect of wall, of rotational dispersion coefficient is derived. The derived expression of rotational dispersion coefficient can be employed to the inhomogeneous and non-isotropic turbulent flows.Furthermore it can be expanded to three-dimensional turbulent flows and serves the theoretical basis for solving the turbulent flow of fiber suspension.