Abstract: The objective of the present study is to investigate the effect of flow parameters on the free convection and mass transfer of an unsteady magnetohydrodynamic flow of an electrically conducting, viscous, and incompressible fluid past an infinite vertical porous plate under oscillatory suction velocity and thermal radiation. The Dufour (diffusion thermo) and Soret (thermal diffusion) effects are taken into account. The problem is solved numerically using the finite element method for the velocity, the temperature, and the concentration field. The expression for the skin friction, the rate of heat and mass transfer is obtained. The results are presented numerically through graphs and tables for the externally cooled plate (Gr > 0) and the externally heated plate (Gr < 0) to observe the effects of various parameters encountered in the equations.