Abstract: A finite-volume high-resolution numerical model for coupling the shallow water flows and pollutant diffusions was presented based on using a hybrid TVD scheme in space discretization and a Runge-Kutta method in time discretization. Numerical simulations for modelling dam-break, enlarging open channel flow and pollutant dispersion were implemented and compared with experimental data or other published computations. The validation of this method shows that it can not only deal with the problem involving discontinuities and unsteady flows, but also solve the general shallow water flows and pollutant diffusions.